Author: László I. Simándi
Publisher: Springer
Keywords: metal, complexes, catalysis, dioxygen, catalytic, activation, advances
Number of Pages: 352
Published: 2003-01-31
List price: $167.00
ISBN-10: 1402010745
ISBN-13: 9781402010743
The catalytic activation of dioxygen continues to attract interest both due to its biological importance and synthetic potential. Metalloenzymes play crucial roles in metabolism by living organisms. The modelling of metalloenzymes by biomimetic metal complexes helps the search for useful oxidation catalysts and the understanding of their mechanisms of operation. Dioxygen is also the oxidant of choice in emission-free technologies aimed at minimising pollution of the environment, in line with the green chemistry requirements. This volume is devoted to recent progress in the field of catalytic o
Author: A.E. Shilov
Publisher: Springer
Keywords: metal, complexes, catalysis, transition, saturated, hydrocarbons, activation
Number of Pages: 220
Published: 1984-06-30
List price: $194.00
ISBN-10: 9027716285
ISBN-13: 9789027716286
Author: László I. Simándi
Publisher: Springer
Keywords: metal, complexes, catalysis, dioxygen, activation, catalytic
Number of Pages: 412
Published: 1992-07-31
List price: $299.00
ISBN-10: 079231896X
ISBN-13: 9780792318965
The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspect
Authors:Everett A. Jenne, etc.,
Publisher: Piccin Nuova Libraria
Keywords: solution, complexes, metal
Number of Pages: 325
Published: 1986-12
List price: unknow
ISBN-10: 8829906794
ISBN-13: 9788829906796
Author: Olaf Kuhl
Publisher: Wiley
Keywords: complexes, carbene, heterocyclic, functionalised
Number of Pages: 364
Published: 2010-03-22
List price: $165.00
ISBN-10: 0470712155
ISBN-13: 9780470712153
N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin
Authors:J.H. Zagal, Fethi Bedioui, J.P. Dodelet,
Publisher: Springer
Keywords: complexes, metal, macrocyclic
Number of Pages: 814
Published: 2006-07-19
List price: $195.00
ISBN-10: 038728429X
ISBN-13: 9780387284293
The book offers insight into applications and developments of N4 macrocycles complexes in biomimetic electrocatalysis, electroanalysis and energy storage. Chapters are devoted to (i) the chemistry, electronic and electrochemical properties of porphyrin and phthalocyanines and their applications in analytical, photoelectrochemical and energy storage molecular devices, (ii) the use of electropolymerized porphyrins, phthalocyanines and related complexes as electrocatalysts for the activation and the detection of a wide variety of environmentally polluting and biologically relevant molecules, and
Author: Anatoly D. Pomogailo
Publisher: CRC Press
Keywords: complexes, metal, immobilized, polymer, catalysis
Number of Pages: 424
Published: 1999-01-27
List price: $199.95
ISBN-10: 9056991302
ISBN-13: 9789056991302
Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the a
